Skip to Main Content

New Article: Dr. Ataca & collaborators in Advanced Materials

February 12, 2020 9:54 AM
“Unusual Pressure‐Driven Phase Transformation and Band Renormalization in 2D vdW Hybrid Lead Halide Perovskites”

Han Li, Ying Qin, Bohan Shan, Yuxia Shen, Fatih Ersan, Emmanuel Soignard, Can Ataca, Sefaattin Tongay

Dr. Ataca and his collaborators work on high-pressured engineering of Two-Dimensional van der Walls perovskites is published on Advanced Materials and their graphics are selected to be featured inside the cover of the issue.

Advanced Materials, 2020, 1907364


Abstract: The application of high pressure allows control over the unit cell and interatomic spacing of materials without any need for new growth methods or processing while accessing their materials properties in situ. Under these extreme pressures, materials may assume new structural phases and reveal novel properties. Here, unusual phase transition and band renormalization effects in 2D van der Waals Ruddlesden−Popper hybrid lead halide perovskites, which have shown extraordinary optical properties and immense potential in light emission and conversion technologies, are reported. The results show that (CH3(CH2)3NH3)2(CH3NH3)Pb2Br7 (n = 2) layers undergo two distinct phase transitions related to PbBr6 octahedra, butylammonium (BA), and methylammonium (MA) molecule tilting motion that leads to rather unique/anomalous bandgap variation with pressure. In contrast, (CH3(CH2)3NH3)PbBr4 (n = 1) lacks MA molecules and possesses only one pressure‐induced phase transition related to PbBr6 octahedra and BA tilting. In this range, the bandgap reduces monotonically, much similar to other inorganic semiconductors and display surprisingly large redshift from 3 to 2.4 eV. Together with theoretical calculations, this study offers unique insights into these pressure‐induced changes and extends the understanding of these highly anisotropic layered soft organic perovskite materials under extreme conditions.